Synthesis and reactions of the first fluoroalkylated Ni(II) N-confused porphyrins.
نویسندگان
چکیده
The first fluoroalkylated Ni(ii) N-confused porphyrins were synthesized with high regioselectivity and its further alkylation was studied.
منابع مشابه
Inner C-cyanide addition and nucleophilic addition to Ni(II) N-confused porphyrins.
Inner C-cyanide addition and subsequent addition of a methoxy group were observed in the reactions of Ni(II) N-confused tetra(p-tolyl)porphyrin with sodium methoxide and DDQ.
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The oxidation of Ni(II) N-confused porphyrins (NCPs) with azo radical initiators resulted in an unexpected intramolecular nucleophilic substitution reaction via a proposed Ni(III) NCP intermediate, which could be detected by HRMS.
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متن کاملAn x-ray absorption and photoemission study of the electronic structure of Ni porphyrins and Ni N-confused porphyrin.
Investigations of chemical bonding and electronic structure features for polycrystalline (porphyrinato)nickel (II) (NiP, the simplest Ni porphyrin), (5,10,15,20-tetraphenylporphyrinato)nickel (II) (NiTPP) and (2-aza-21-carba-5,10,15,20-tetraphenylporphyrinato)nickel (II) (N-confused NiTPP, NiNCTPP) have been performed by means of high-resolution soft x-ray absorption and x-ray photoemission spe...
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ورودعنوان ژورنال:
- Chemical communications
دوره 42 شماره
صفحات -
تاریخ انتشار 2008